Journal of Spectral Imaging,   Volume 8   Article ID a1   (2019)

Peer reviewed Paper

Application of hyperspectral imaging and chemometrics for classifying plastics with brominated flame retardants

  • Daniel Caballero
  • Marta Bevilacqua
  • José Manuel Amigo
Chemometrics and Analytical Technology, Department of Food Science, Faculty of Science, Rolighedsvej 26, DK-1958, Frederiksberg C, Denmark and Computer Science Department, Research Institute of Meat and Meat Product (IproCar), University of Extremadura, Av/ Ciencias S/N, ES-10003, Cáceres, Spain

 https://orcid.org/0000-0003-2822-0323
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Chemometrics and Analytical Technology, Department of Food Science, Faculty of Science, Rolighedsvej 26, DK-1958, Frederiksberg C, Denmark.

 https://orcid.org/0000-0002-3361-9219
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 Corresponding Author
Chemometrics and Analytical Technology, Department of Food Science, Faculty of Science, Rolighedsvej 26, DK-1958, Frederiksberg C, Denmark.
[email protected]
 https://orcid.org/0000-0003-1319-1312
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Most plastics need to incorporate flame retardants to meet fire safety standards requirements. The amount and the type of flame retardants can differ, so that in waste plastics a large variety of polymers and flame retardants can be found. The recycling of plastics containing flame retardants is increasing. However, only plastics of the same polymer type and the same additive content can be recycled together. Three models based on different chemometrics techniques applied to hyperspectral imaging in the near infrared range were developed [partial least square-discriminant analysis, decision tree (DT) and hierarchical model (HM)]. Optimal results were obtained for all classification techniques. HM shows the highest error at all levels due to the noisy spectra of the black plastics. However, DT classification gave outstanding results, considering that the sensitivity was higher than 0.9 in all cases. Thus, the application of DT with hyperspectral imaging could be used to sort plastic samples with respect to the type of polymer and the flame retardant used with a high degree of accuracy in an automated way. These findings are highly valuable for the plastic and waste management industries.

Keywords: waste recycling, plastics recycling, NIR hyperspectral imaging, polymer, flame retardants, decision tree, hierarchical classification, partial least square-discrimination analysis

 

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